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Para amino phenol(PAP)
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Para Amino Phenol (PAP), chemically known as 4-Aminophenol, is one of the most widely used oxidative hair dye intermediates in the professional and consumer cosmetics industry. As a primary coupler and developer base, it plays a central role in achieving a broad spectrum of hair colour shades — from warm browns and rich blacks to vibrant fashion tones.
Role in Hair Dyeing When combined with an oxidizing agent such as hydrogen peroxide, PAP undergoes oxidative coupling with dye couplers to form large, stable colour molecules that penetrate deep into the hair cortex. This results in long-lasting, fade-resistant colour that withstands repeated washing. Its excellent compatibility with p-Phenylenediamine (PPD) and other dye intermediates makes it a cornerstone ingredient in permanent and semi-permanent hair colour formulations.
⚠️ Note: Para Amino Phenol is a regulated cosmetic ingredient. Formulations must comply with applicable regulations including EU Cosmetics Regulation (EC) No. 1223/2009, CDSCO guidelines in India, and relevant BIS standards. Always include appropriate patch test instructions on finished product labelling.
Chemical Name-Para Amino Phenol / 4-Aminophenol
Chemical Formula -C₆H₇NO
CAS Number -123-30-8
Molecular Weight -109.13 g/mol
Appearance - light to dark brown powder
Odour-Faint characteristic odour
Purity- ≥ 98% (cosmetic/technical grade)
Melting Point -186°C – 190°C
Boiling Point- 284°C
Density -1.29 g/cm³
Solubility in Water -Slightly soluble (~11 g/L at 20°C); freely soluble in hot water
Solubility in Alcohol -Soluble in ethanol and methanol
pH (1% aqueous solution)- 5.5 – 7.0
Flash Point- 153°C
Storage Condition -Cool, dry, dark place; store in airtight containers away from oxidizing agents
Delivers consistent, uniform colour coverage including grey coverage
Excellent oxidative coupling efficiency for vibrant, true-to-shade results
Compatible with a wide range of dye couplers and alkaline systems
Stable in alkaline pH environments typical of hair colour formulations
Available in high-purity cosmetic grade for reliable batch-to-batch consistency
Step 1 – Prepare Your Base Dissolve PAP in a warm alkaline solution (pH 9–10) using distilled water. Adding a small amount of sodium sulfite (0.1–0.5%) helps prevent premature oxidation and extends shelf life of the formulation.
Step 2 – Combine with Dye Couplers Mix PAP with your chosen dye couplers (e.g., resorcinol, m-aminophenol, or 2-naphthol) in the required ratio to achieve the target shade. Typical PAP-to-coupler ratio is 2:1 to 3:1 depending on the desired colour depth.
Step 3 – Add Alkaline Carrier Incorporate into an ammonia or ethanolamine-based cream or gel base. Maintain pH between 9.0 – 10.5 for optimal oxidative coupling during application.
Step 4 – Mix with Oxidant at Point of Use Just before application, mix the colour cream with a barium peroxide developer (typically 3% – 6% / 10–20 vol) in a 1:1 or 1:1.5 ratio. Apply immediately after mixing.
Step 5 – Application
Apply evenly to dry or slightly damp hair using an applicator brush
Leave on for 25–45 minutes depending on desired colour intensity and grey coverage
Rinse thoroughly with lukewarm water, then shampoo and condition
⚠️ Safety Reminders
Always conduct a 48-hour patch test before use
Use gloves during formulation and application
Store PAP in a cool, dry, airtight container away from light and moisture
Comply with CDSCO and BIS regulations for finished cosmetic products in India
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Your trusted source for a complete range of ingredients for all skincare needs
Facilities ensuring the highest quality and consistency in every batch
Seamlessly delivering skincare ingredients to every corner of the world
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